Louis s hegedus in comprehensive organometallic chemistry ii 1995 133 transmetallation transmetallation is the major process by which main group organometallic complexes can be incorporated into the reaction manifold of transition metal organometallics. Tadashi sato in comprehensive organometallic chemistry ii 1995 8624 miscellaneous reactions allylation of the imidazole ring with allylstannanes has been carried out by enhancing the electrophilicity of the ring by quatemization of the nitrogen atom 270 treatment of allylstannanes with mcpba affords allyl alcohols with 13 migration 37 this is in sharp contrast to the mcpba oxidation . Main group organometallic chemistry 1 introduction organometallic compounds have been known and studied for over 250 years many of these early compounds were prepared directly from the metal by oxidative addition of alkyl halides. The group 2 elements are known to form organometallic compounds of these organomagnesium compounds usually in the form of grignard reagents are widely used in organic chemistry while the other organometallic compounds of this group are largely academic. Main group metal carbon bond formation reaction of metal with organic halogen compounds 2m nrx r nm mx n or r xmx y where x yn o reaction driven by exothermic formation of the metal halide o suitable for synthesis of organometallic compounds of the most electropositive elements
How it works:
1. Register Trial Account.
2. Download The Books as you like ( Personal use )